Toast the Pecans: In a dry skillet over medium heat, toast the pecans until fragrant and slightly darker in color. Alternatively, place them on a sheet pan and bake in a 350°F preheated oven for about 10 minutes. This step enhances their natural nuttiness.
Prepare the Spice Blend: In a medium-sized bowl, combine the sugar, kosher salt, and chipotle powder. Make sure the bowl is large enough to accommodate the pecans later.
Coat the Pecans: In a large nonstick skillet over medium heat, stir together the water, honey, and olive oil until the mixture begins to bubble. Add the toasted pecans and stir until they’re fully coated in the sticky glaze.
Toss and Cool: Transfer the glazed pecans into the spice blend, tossing them until evenly coated. Spread the pecans in an even layer onto a sheet pan and let them cool to room temperature for about an hour. This step ensures a crisp, flavorful coating.